Elizabeth J. Biddinger

Associate Professor

Main Affiliation

Chemical Engineering

Areas of Expertise/Research

  • Biomass Utilization
  • CO2 Utilization
  • Catalysis
  • Chemical Engineering
  • Decarbonization
  • Electrochemical Engineering
  • Energy Storage Technologies
  • Ionic Liquids

Building

Steinman Hall

Office

311

Fax

212-650-6323

Elizabeth J. Biddinger

Elizabeth J. Biddinger

Profile

Elizabeth J. Biddinger is an Associate Professor in Chemical Engineering at The City College of New York.  Her research interests encompass green chemistry and energy concerns.  She has expertise in catalysis, electrochemistry, alternative solvents, green chemistry and sustainable engineering. In particular, she is interested in the electrification of chemical processes that transform wastes or renewable resources into valuable materials, chemicals and fuels for decarbonization and sustainability; and the use of ionic liquids and alternative solvents in electrochemical systems for improved performance and safety. Current research projects in her group include developing strategies for decarbonizing the chemical industry using renewable electricity (Sloan Foundation), understanding the reaction mechanisms and kinetics for the electroreduction of biomass-derived furanics (DOE), storing and releasing hydrogen from liquid organic hydrogen carriers (LOHCs) electrochemically (DOE & NSF), utilization of ionic liquids as electrolyte additives in CO2 electroreduction (NSF), investigation of ionic liquid mixtures for batteries used in space applications (NASA), and recovery of critical materials from waste-to-energy ash using ionic liquids and electrochemistry (ARPA-E).

Professor Biddinger has been recognized for her research with multiple awards since being at City College including the 2018 US Department of Energy Early Career Award for investigation of the kinetics and reaction mechanisms for biomass electroreduction, the 2016-2017 Electrochemical Society - Toyota Young Investigator Fellowship for studying switchable electrolytes for battery safety, and the 2014 CUNY Junior Faculty Research Award in Science and Engineering (JFRASE) sponsored by the Sloan Foundation to study CO2 electroreduction.

Professor Biddinger has held several leadership posts in professional societies including Director in the Catalysis and Reaction Engineering Division of the American Institute of Chemical Engineers (AIChE), member of the Publications Subcommittee of the Electrochemical Society (ECS), Secretary/Treasurer and Student Awards Chair for the Industrial Electrochemistry & Electrochemical Engineering Division of ECS. In the past, she also served as chair and vice-chair of the Central Ohio Professional Section of American Institute of Chemical Engineers. She is also an Associate Editor of ACS Sustainable Chemistry & Engineering.

Prior to joining City College in August 2012, Prof. Biddinger was a Post-doctoral Fellow at the Georgia Institute of Technology studying alternative solvent systems for green chemistry and sustainable engineering applications, including CO2 capture, nanoparticle synthesis and homogeneous catalyst recycle.  She received her PhD in 2010 in Chemical Engineering from The Ohio State University and her BS in 2005 in Chemical Engineering from Ohio University.  Her research at Ohio State involved the development and investigation of nitrogen-containing carbon nanostructures as oxygen reduction electrocatalysts for PEM and direct methanol fuel cells.  In the past, she also worked on electrocatalysis development for the production of hydrogen by ammonia electrolysis

Education

Georgia Institute of Technology, Atlanta, Georgia, 2010-2012
Postdoctoral Fellow, Chemical and Biomolecular Engineering

The Ohio State University, Columbus, Ohio
Ph.D., Chemical and Biomolecular Engineering, 2010

Ohio University, Athens, Ohio
B.S., Chemical Engineering, Mathematics minor, Magna Cum Laude, 2005

Research Interests

Electrochemical Reaction Engineering; Catalysis; Separations; Alternative Solvents; Ionic Liquids; Decarbonization; Green Chemistry & Sustainable Engineering

Publications

For the most updated list of publications, please see my Google Scholar page. 

Journal Articles

 

  • A.S. May, E.J. Biddinger*, Speciation of Potential-Dependent Fouling on Copper Foil Electrodes During Electrochemical Hydrogenation and Hydrogenolysis of Furfural in Strong Acid,” 2023, accepted.
  • S. Sharifi Golru, A.S. May, E.J. Biddinger*, “Modifying Copper Local Environment with Electrolyte Additives to Alter CO2 Electroreduction vs Hydrogen Evolution,” ACS Catalysis, 13 (2023), 7831-7843.
  • D. Mallapragada, Y. Dvorkin, M. Modestino, D. Esposito, W. Smith, B.-M. Hodge, M. Harold, V. Donnelly, A. Nuz, C. Bloomquist, K. Baker, L. Grabow, Y. Yan, N.N. Rajput, R. Hartman, E. Biddinger, E. Aydil, A. Taylor, “Decarbonization of the Chemical Industry through Electrification: Barriers and Opportunities,” Joule, 7 (2023), 23-41.
  • A.S. May, E.J. Biddinger*, “Modeling Competing Kinetics between Electrochemical Reduction of Furfural on Copper and Homogeneous Side Reactions in Acid,” Energy & Fuels, 36 (2022), 11001-11011. 
  • S. Oh, M.J. Keating, E.J. Biddinger*, “Physical and Electrochemical Properties of Ionic-Liquid-and Ester-Based Cosolvent Mixtures with Lithium Salts,” Industrial & Engineering Chemistry Research, 61 (2022), 12118-12131.
  • S. Sharifi Golru, E.J. Biddinger*, “Effect of additives in aqueous electrolytes on CO2 electroreduction,” Chemical Engineering Journal, 428 (2022), 131303
  • A.S. May, S.M. Watt, E.J. Biddinger*, “Kinetics of Furfural Electrochemical Hydrogenation and Hydrogenolysis in Acidic Media on Copper,” Reaction Chemistry & Engineering, 6 (2021), 2075-2086.
  • Y. Jung, S. Sharifi Golru, T.-D. Li, E.J. Biddinger, R.S. Tu, X. Chen, “Tuning water-responsiveness with Bombyx mori silk-silica nanoparticle composites,” Soft Matter, 17 (2021), 7817-7821.
  • S. Jung, S. Podder, J. Chen, E.J. Biddinger*, “Structure-Property Relationships of Silylamine-Type Reversible Ionic Liquids for Use as Switchable Electrolytes,” Journal of The Electrochemical Society, 168, (2021), 036516.
  • S. Sharifi Golru, E.J. Biddinger*, “Effect of Anion in Diluted Imidazolium-based Ionic Liquid/Buffer Electrolytes for CO2 Electroreduction on Copper,” Electrochimica Acta, (2020), 136787.
  • A. Aydogan, J. Usman, D.G. Peck, S. Jung, K. Li, E.J. Biddinger, “Golden Pothos Viability in Engineered Mixed Bed Growth Media Contain Ionic Liquids for Plant-Based Building Air Filtration,” Rhizosphere, 15 (2020), 100209.
  • A.S. May, E.J. Biddinger*, “Strategies to Control Electrochemical Hydrogenation and Hydrogenolysis of Furfural and Minimize Undesired Side Reactions,” ACS Catalysis, 10, (2020), 3212-3221. (invited Viewpoint review)
  • A.N. Karaiskakis (co-first author), S. Sharifi Golru (co-first author), E.J. Biddinger*, “Effect of Electrode Geometry on Selectivity and Activity in CO2 Electroreduction,” Industrial & Engineering Chemistry Research, 58, (2019), 22506-22515.
  • S. Jung, A.N. Karaiskakis, E.J. Biddinger*, “Enhanced Activity for Electrochemical Hydrogenation and Hydrogenolysis of Furfural to Biofuel using Electrodeposited Cu Catalysts,” Catalysis Today, 323, (2019), 26-34.
  • S. Jung, E.J. Biddinger*, “Controlling Competitive Side Reactions in the Electrochemical Upgrading of Furfural to Biofuels,” Energy Technology, 6, (2018), 1370-1379.
  • S. Groveman, J. Peng, B. Itin, I. Diallo, L.M. Pratt, A. Greer, E.J. Biddinger, S.G. Greenbaum, C.M. Drain, L. Francesconi, M. Vittadello*, “The Role of Ozone in the Formation and Structural Evolution of Graphene Oxide Obtained from Nanographite,” Carbon, 122 (2017), 411-421.
  • A.N. Karaiskakis, E.J. Biddinger*, “Evaluation of Surface Reconstruction Impacts on Rough Electrodeposited Cu-Based Catalysts for CO2 Electroreduction,” Energy Technology, 5 (2017), 901-910. 
  • S. Jung, E.J. Biddinger*, “Electrocatalytic Hydrogenation and Hydrogenolysis of Furfural and the Impact of Homogeneous Side Reactions of Furanic Compounds in Acidic Electrolytes,” ACS Sustainable Chemistry & Engineering, 4 (2016), 6500-6508. 
  • S. Shrestha, M. Nagib, E.J. Biddinger*, “Size-Controlled Synthesis of Palladium Nanospheres by Pulse Electrodeposition in 1-Butyl-3-MethylImidazolium Chloride Ionic Liquid,” Journal of The Electrochemical Society, 163 (2016), D74-D82.
  • S. Shrestha, E.J. Biddinger*, “Palladium Electrodeposition in 1-Butyl-1-Methylpyrrolidinium Dicyanamide Ionic Liquid,” Electrochimica Acta, 174 (2015), 254-263. 
  • J.D. Jimenez, S. Jung, E.J. Biddinger*, “Ionicity of Silylamine-Type Reversible Ionic Liquids as a Model Switchable Electrolyte,” Journal of The Electrochemical Society, 162 (2015), H460-H465.
  • J.R. Switzer, A.L. Ethier, E.C. Hart, K.M. Flack, A.C. Rumple, J.C. Donaldson, A.T. Bembry, O.M. Scott, E.J. Biddinger, M. Talreja, M.-G. Song, P. Pollet, C.A. Eckert*, C.L. Liotta*, “Design, Synthesis, and Evaluation of Nonaqueous Silylamines for Efficient CO2 Capture,” ChemSusChem, 7 (2014), 299-307
  • A.L. Ethier, E.C. Hart, S.R. Saunders, E.J. Biddinger, A.Z. Fadhel, C. Dilek, P. Pollet, C.A. Eckert*, C.L. Liotta*, “Reversible Ionic Surfactants for Gold Nanoparticle Synthesis,” Green Materials, 2 (2014), 54-61.
  • X. Bao, X. Nie, D. von Deak, E.J. Biddinger, W. Luo, A. Asthagiri, U.S. Ozkan, C.M. Hadad*, “A First-Principles Study of the Role of Quaternary-N Doping on the Oxygen Reduction Reaction Activity and Selectivity of Graphene Edge Sites,” Topics in Catalysis, 56 (2013), 1623-1633.
  • J.R. Switzer, A.L. Ethier, K.M. Flack, E.J. Biddinger, L. Gelbaum, P. Pollet, C.A. Eckert*, C.L. Liotta*, “Reversible Ionic Liquid Stabilized Carbamic Acids: A Pathway Toward Enhanced CO2 Capture,” Industrial & Engineering Chemistry Research, 52 (2013), 13159-13163.
  • M. Gonzalez-Miquel, M. Talreja, A.L. Ethier, K. Flack, J.R. Switzer, E.J. Biddinger, P. Pollet, J. Palomar, F. Rodriguez, C.A. Eckert*, C.L. Liotta*, "COSMO-RS Studies: Structure-Property Relationships for CO2 Capture by Reversible Ionic Liquids," Industrial & Engineering Chemistry Research, 51 (2012), 16066-16073.
  • A.L. Rohan, J.R. Switzer, K.M. Flack, R.J. Hart, S. Sivaswamy, E.J. Biddinger, M. Talreja, M. Verma, S. Faltermeier, P.T. Nielsen, P. Pollet, G.F. Schuette, C.A. Eckert*, C.L. Liotta*, “The Synthesis and the Chemical and Physical Properties of Non-Aqueous Silylamine Solvents for Carbon Dioxide Capture,” ChemSusChem, 5(2012), 2181-2187.
  • D. von Deak, D. Singh, E.J. Biddinger, J.C. King, B. Bayram, J.T. Miller, U.S. Ozkan*, “Investigation of Sulfur Poisoning of CNx Oxygen Reduction Catalysts for PEM Fuel Cells,” Journal of Catalysis, 285 (2012), 145-151.
  • E.J. Biddinger, D. von Deak, D. Singh, H. Marsh, B. Tang, D.S. Knapke, U.S. Ozkan*, “Examination of Catalyst Loading Effects on the Selectivity of CNx and Pt/VC ORR Catalysts using RRDE,” Journal of The Electrochemical Society, 158 (2011), B402-B409.
  • D. von Deak, E.J. Biddinger, U.S. Ozkan*, “Carbon Corrosion Characteristics of CNx Nanostructures in Acidic Media and Implications for ORR Performance,” Journal of Applied Electrochemistry, 41 (2011), 757-763.
  • E.J. Biddinger, U.S. Ozkan*, “Role of Graphitic Edge Plane Exposure in Carbon Nanostructures for Oxygen Reduct on Reaction,” Journal of Physical Chemistry C, 114 (2010), 15306-15314.
  • E.J. Biddinger, D. von Deak, H. Marsh, U.S. Ozkan*, “RRDE Catalyst Ink Aging Effects on Selectivity to Water Formation in ORR,”Electrochemical and Solid-State Letters, 13 (2010), B98-B100.
  • E.J. Biddinger, D.S. Knapke, D. von Deak, U.S. Ozkan*, “Effect of Sulfur as a Growth Promoter for CNx Nanostructures as PEM and DMFC ORR Catalysts,” Applied Catalysis B: Environmental, 96 (2010), 72-82.
  • X. Bao, D. von Deak, E.J. Biddinger, U.S. Ozkan*, C.M. Hadad, “A Computational Exploration of the Oxygen Reduction Reaction over a Carbon Catalyst Containing a Phosphinate Functional Group,” Chemical Communications, 46 (2010), 8621-8623.
  • D. von Deak, E.J. Biddinger, K.A. Luthman, U.S. Ozkan*, “The Effect of Phosphorus in Nitrogen-Containing Carbon Nanostructures on Oxygen Reduction in PEM Fuel Cells,” Carbon, 48 (2010), 3637-3639.
  • M.P.Woods, E.J. Biddinger, P.H. Matter, B. Mirkelamoglu, U.S. Ozkan*, “Correlation Between Oxygen Reduction Reaction and Oxidative Dehydrogenation Activities over Nanostructured Carbon Catalysts,” Catalysis Letters, 136 (2010), 1-8.
  • E.J. Biddinger, D. von Deak, U.S. Ozkan*, “Nitrogen-Containing Carbon Nanostructures as Oxygen-Reduction Catalysts,” Topics in Catalysis, 52 (2009), 1566-1574.
  • E.P. Bonnin, E.J. Biddinger, G.G. Botte*, “Effect of Catalyst on Electrolysis of Ammonia Effluents,” Journal of Power Sources, 182 (2008), 284-290.
  • E.J. Biddinger, U.S. Ozkan, “Methanol Tolerance of CNx Oxygen Reduction Catalysts,” Topics in Catalysis, 46 (2007), 339-348.
  • P.H. Matter, E. Wang, M. Arias, E.J. Biddinger, U.S. Ozkan*, “Oxygen Reduction Reaction Activity and Surface Properties of Nanostructured Nitrogen-Containing Carbon,” Journal of Molecular Catalysis A:  Chemical, 264 (2007), 73-81.
  • P.H. Matter, E. Wang, M. Arias, E.J. Biddinger, U.S. Ozkan*, “Oxygen Reduction Reaction Catalysts Prepared from Acetonitrile Pyrolysis over Alumina-Supported Metal Particles,” Journal of Physical Chemistry B, 110 (2006), 18374-18384.


Book Chapter

  • P.H. Matter, E.J. Biddinger, U.S. Ozkan*, “Non-precious metal oxygen reduction catalysts for PEM fuel cells,” Catalysis, Spivey, J.J., Ed. The Royal Society of Chemistry, Cambridge, UK, Vol. 20 (2007), 338-361.

Magazine Articles

  • E.J. Biddinger*, M. A. Modestino, “Electro-organic Syntheses for Green Chemical Manufacturing,” ECS Interface, Fall 2020 issue, 29, 43-47.

Refereed Conference Proceedings

  • Simson*, E.J. Biddinger, L. Broughton, “Program Evaluation of a High School Summer Bridge Program in Chemistry and Engineering,” American Society of Engineering Education, 2019 Meeting, Paper ID #27651.
  • E.J. Biddinger*, S. Jung, S. Podder, J. Chen, “Tunable Reversible Ionic Liquids: Structurally Determined Property Manipulation,” ECS Transactions, 86 (14), (2018), 133-140.
  • S. Shrestha, M. Nagib, E.J. Biddinger*, “Pd Nanoparticle Formation during Constant Potential Electrodepositions in Ionic Liquids,” ECS Transactions, 75 (15), (2016), 649-655.
  • E.J. Biddinger*, J.D. Jimenez, “(3-Aminopropyl)triethoxysilane as a Model Silylamine Reversible Ionic Liquids Used as a Reversible Electrolyte,” ECS Transactions, 64 (2014), 71-81.
  • S. Shrestha, E. Gjoka, E.J. Biddinger*, “Electrodeposition of Palladium in 1-Butyl-3-Methylimidazolium Chloride Ionic Liquid,” ECS Transactions, 64 (2014), 267-274.